Weikang Zhang, Chong Meng, Yan Liu, Yawen Tang, Feng Li. Although imine formation is favored over nitrile production in the first hour, the imine product is intermittent and disappeared over time. A Proton-Switchable Bifunctional Ruthenium Complex That Catalyzes Nitrile Hydroboration. This article is cited by iii Once stabilized by a Lewis acid-base complexation the imine salt can accept a second hydride to form a dianion. Zhou Tang, Cristina Tejel, Marc Martinez de Sarasa Buchaca, Martin Lutz, Jarl Ivar van der Vlugt, Bas de Bruin. Ritwika Ray, Arijit Singha Hazari, Goutam Kumar Lahiri, Debabrata Maiti. Preparation of aromatic nitriles via direct oxidative conversion of benzyl alcohols, aldehydes and amines with pentylpyridinium tribromide in aqueous NH4OAc. Pyridyl-substituted mesoionic triazolylidene ruthenium cymene complexes catalyze the oxidation of both aromatic and aliphatic amines to nitriles with high activity and selectivity under benign conditions using dioxygen as the terminal oxidant. Find more information about Crossref citation counts. J. M. Stubbs, K. F. Firth, B. J. Bridge, K. J. Berger, R. J. Hazlehurst, P. D. Boyle, J. M. Blacquiere. Au Kyle M. Lambert, James M. Bobbitt, Sherif A. Eldirany, Kenneth B. Wiberg, and William F. Bailey . Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information Examining the early stages of thermal oxidative degradation in epoxy-amine resins. Control experiments support a nitrile oxide intermediate mechanism for this novel class of oxidative cyclization reactions. Laura M. Dornan, Qun Cao, Mark J. Muldoon.

Silylative reduction of nitriles under transition metal-free conditions converts alkyl and (hetero)aryl nitriles efficiently to primary amines under mild conditions. Pei Chen, Qian-Qian Zhang, Jia Guo, Lu-Lu Chen, Yan-Bo Wang, Xiao Zhang. Xinjiang Cui, Zhangjun Huang, Antoine P. van Muyden, Zhaofu Fei, Tao Wang, Paul J. Dyson. o Fetching data from CrossRef. O 3 (111) facets. Double Dehydrogenation of Primary Amines to Nitriles by a Ruthenium Complex Featuring Pyrazole Functionality. You have to login with your ACS ID befor you can login with your Mendeley account. http://pubs.acs.org/page/copyright/permissions.html. Boosting Hydrogen Production by Anodic Oxidation of Primary Amines over a NiSe Nanorod Electrode. Kishore Natte, Rajenahally V. Jagadeesh, Muhammad Sharif, Helfried Neumann, Matthias Beller. Aromatic as well as aliphatic nitriles are reduced to the corresponding primary amines. Parvathy, Naveen V. Kulkarni, Dineshchakravarthy Senthurpandi. Kuei-Nin T. Tseng, Jeff W. Kampf, and Nathaniel K. Szymczak .

/RCN couples. 2 Chidambaram Gunanathan and David Milstein . Lillian V. A. Hale and Nathaniel K. Szymczak . Nitrogen-Containing Liquid Organic Hydrogen Carriers: Progress and Prospects. Weiguang Chen, Julien Egly, Amalia I. Poblador-Bahamonde, Aline Maisse-Francois, Stéphane Bellemin-Laponnaz, Thierry Achard. Nitrile Synthesis by Aerobic Oxidation of Primary Amines and The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Miguel A. Esteruelas, Virginia Lezáun, Antonio Martínez, Montserrat Oliván, and Enrique Oñate .

Get article recommendations from ACS based on references in your Mendeley library. However, the (super)stoichiometric quantities of undesired by-products which are inevitably produced in these methods may be wasteful, unsustainable and environmentally deleterious. Sondomoyee K. Moromi, S.M.A.

Users are Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Citations are the number of other articles citing this article, calculated by Crossref and updated daily.

“Nanorust”-catalyzed Benign Oxidation of Amines for Selective Synthesis of Nitriles. 91 publications. The catalyst system tolerates oxidizable functionality and is selective for the dehydrogenation of primary amines (−CH2NH2) in the presence of amines without α-CH hydrogens. Please enable JavaScript O Baoqiang Niu, Fei Lu, Hong-Yu Zhang, Yuecheng Zhang, Jiquan Zhao. Yu Liu, Qiao-Lin Wang, Zan Chen, Hua Li, Bi-Quan Xiong, Pan-Liang Zhang, Ke-Wen Tang. 4 René Pretorius, Juan Olguín, and Martin Albrecht . and Ir Complexes upon Deprotonation and Their Application in Catalytic Carbene Carbonylation Reactions. Catalytic Acceptorless Dehydrogenation of Amines with Ru(PR2NR′2) and Ru(dppp) Complexes. Ritwika Ray, Shubhadeep Chandra, Vishal Yadav, Prasenjit Mondal, Debabrata Maiti, Goutam Kumar Lahiri. Synthesis of nitriles from amines using nanoscale Co tBu2

Lillian V. A. Hale, Tanmay Malakar, Kuei-Nin T. Tseng, Paul M. Zimmerman, Ankan Paul, and Nathaniel K. Szymczak . Kazuya Yamaguchi, Ning Xu, Xiongjie Jin, Kosuke Suzuki, Noritaka Mizuno.

Svenja Budweg, Kathrin Junge, Matthias Beller.

-based catalysts via sustainable aerobic oxidation. via

Fabrizio Bottaro, Ahmad Takallou, Ahmad Chehaiber, Robert Madsen. This article is licensed under a Creative Commons Attribution 3.0 Unported For reproduction of material from all other RSC journals. Susanta Hazra, Ekta Malik, Abhishek Nair, Vikas Tiwari, Pritam Dolui, Anil J. Elias. 3 O) Facile Oxidation of Primary Amines to Nitriles Using an Oxoammonium Salt. Bis(pyridylimino)isoindolato (BPI) Osmium Complexes: Structural Chemistry and Reactivity.

O Bn2 Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis. Primary amines contain the -NH 2 group. Photocatalytic selective aerobic oxidation of amines to nitriles over Ru/γ-Al Find more information about Crossref citation counts. Regioselective Acceptorless Dehydrogenative Coupling of N-Heterocycles toward Functionalized Quinolines, Phenanthrolines, and Indoles. Auto-Tandem Catalysis with Ruthenium: From that the correct acknowledgement is given with the reproduced material. Catalytic hydrogenation of nitriles to amines by nonclassical ruthenium hydride complexes derived from PNP pincer ligands is described.

Pengqing Ye, Yinlin Shao, Leping Xie, Keting Shen, Tianxing Cheng, Jiuxi Chen. Lillian V. A. Hale, N. Marianne Sikes, Nathaniel K. Szymczak. Gibbon, Benjamin Gabriele, Mikhail Malanin, Klaus-Jochen Eichhorn. Extending the Chemistry of Hexamethylenetetramine in Ruthenium-Catalyzed Amine Oxidation. Daniil S. Ovoshchnikov, Baira G. Donoeva, and Vladimir B. Golovko . S 1

‐Heterocycles by N Tatsuki Utsumi, Kenta Noda, Daichi Kawauchi, Hirofumi Ueda, Hidetoshi Tokuyama. Catalytic Aerobic Dehydrogenatin of Synthesis and structure of mono and bis {1,3-bis(2- pyridylimino)isoindoline} supported 3d transition metal complexes. o Information about how to use the RightsLink permission system can be found at

to access the full features of the site or access our, Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland, Creative Commons Attribution 3.0 Unported Experimental procedures and spectral data. Efficient Oxidative Dehydrogenation of N-Heterocycles over Nitrogen-Doped Carbon-Supported Cobalt Nanoparticles. Selective Oxidation of Amines to Imines or Nitriles by Manganese Dioxide in Air.

Licence. Electronic Supporting Information files are available without a subscription to ACS Web Editions. Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (κ2- Variation of reaction conditions provided valuable mechanistic insights and resulted in a highly efficient protocol for nitrile formation with maximum turnover numbers around 10 000.

2 ) Cooperative Complex. Carbohydrate-Functionalized 1,2,3-Triazolylidene Complexes for Application in Base-Free Alcohol and Amine Oxidation. Your Mendeley pairing has expired.

Transition metal-catalyzed dehydrogenation of amines. 1, Hunan Street, Liaocheng, Shandong 252059, China, Oxidize Amines to Nitrile Oxides: One Type of Amine Oxidation and Its Application to Directly Construct Isoxazoles and Isoxazolines, Your Mendeley pairing has expired. )-thioether-functionalised NHC ligands. Cited by. Acceptorless dehydrogenation of N -heterocycles by supported Pt catalysts. The unprecedented strategy of the oxidation of an amine directly to a nitrile oxide was used in this cyclization process. Mengdi Zhao, Wei Zhang, and Zengming Shen . 2. N

Nitrogen-coordinated cobalt nanocrystals for oxidative dehydrogenation and hydrogenation of N-heterocycles. Charge effects regulate reversible CO